Distilling research on the subject...
The most reliable supercharger pulley upgrade is to machine down the stock pulley from 74mm to 69mm, and have eurocharged or others put a tune on it. The stock belt still fits. This with tune is probably good for 30 hp., very noticeable because boost increase is across the rpm range and the tune will improve throttle response. This is very low risk.
There is a seller on ebay with machined stock pulley for $699, and $150 rebate if you send them yours.
The other solutions with much smaller pulleys for the supercharger are more commonly aluminum and prone to failure from fatigue, sometimes spectacularly. Better add the scatter shield if you do, or you will be buying a new hood too. The much smaller radius also invites belt slippage and fatigue, and requires non standard belt. If a SC pulley can be found in stainless or titanium, it might be worth a try..
The crank pulley will certainly have the biggest effect, but costs more, needs a non standard belt, and overspeed's all the accessories. If going this route, you might as well combine with the machined SC pulley for maximum effect, and get one tune session. Turn off traction control at your peril, and the car will need frequent new rear tires. This is well over 400 hp at the flywheel.
Increased boost pressure will increase intake air Temps dramatically, and hot weather can provoke the ecu to mute performance or even disengage the SC with overtemp faults, so, if adding alot more boost you will need a better intercooler pump to increase flow, use Johnson 10-24489-03 CM30 12V 3/4" Pump.
Its a slippery slope you are on...hehe
Next mod is cams, gives it a mean sexy idle and another bump in hp. More money.
Annnd, probably bigger injectors.
And if you do all that, best upgrade the differential, as this is the weakest link in the drivetrain.
These cars can get close to 500 hp, but without drag slicks it can't be connected to the pavement. See the dragtimes web site for '32 and srt/6 times, some of the reports give the recipe for speed they used.
My SLK32 is a relatively pristine 32k miles example, and the most I would do is machine the SC pulley and tune, then swap wheels for ultralight forged ones to lose over 40 lbs of unsprung mass and rotating inertia.
Even without mods it is a joy to drive and will light up the traction control at will, even over 50mph. Stories of melted pistons and other gruesome costly failures curb my enthusiasm for more. If I had a '32 that wasn't as nice that could get down and dirty, this mod list would have been implemented.
Happy Motoring...